Why Do Some Ceramic Bodies Require Binders?
Why Do Some Ceramic Bodies Require Binders?
In ceramic production, a common phenomenon arises: with the same formulation and the same forming process, some products absolutely require binders — without them, they simply cannot be made; while other products can be produced normally without any binder.
Why?
2.1 Only "Weak Bonds" Between Particles
Before firing, ceramic bodies have no true chemical bonds between particles. What holds them in shape?
- Capillary force: Negative pressure from water menisci between particles "pulls" them together
- Van der Waals force: Weak physical attraction between particles
- Limited bonding: Colloidal properties of clay minerals themselves
2.2 Different Forming Methods, Different "Fragility Levels"
| Forming Method | Moisture Content | Green Strength | Fragility Level |
|---|---|---|---|
| Dry Pressing | 5%–7% | Relatively high | Relatively low |
| Roller Forming | 15%–18% | Moderate | Moderately fragile |
| Slip Casting | 18%–20% | Lowest | Most fragile |
3.1 Thin-Walled Products — Inherently Insufficient Strength
Typical products: Thin-bodied porcelain, high-end tableware, thin tiles, art porcelain.
The thinner the wall, the lower the flexural strength. A bowl body with 3mm wall thickness may have only one-third the flexural strength of an 8mm body. During demolding, trimming, and handling, even slight external force can cause edge chipping, corner damage, and cracking.
3.2 Large-Format Products — Self-Weight Is the Threat
Typical products: Large-format tiles (e.g., 900×1800mm), large sanitary ware (toilets, bathtubs), large art pieces.
The problem with large-format bodies is not thin walls but excessive self-weight. A toilet body can weigh 20–30 kg. During demolding, flipping, and handling, the torque and stress the body bears far exceed those of smaller products.
3.3 Complex Shapes — Stress Concentration
Typical products: Complex sanitary ware, carved tableware, complex-shaped art porcelain.
Complex shapes mean uneven wall thickness. Thick and thin sections shrink at different rates during drying, creating stress concentration at the transitions — highly prone to cracking.
3.4 High Lean-Material Formulations — Lacking "Natural Binder"
Typical products: High-whiteness tableware, premium sanitary ware, high-end tiles.
In traditional ceramic formulations, clay (especially ball clay and bentonite) serves as a natural "binder," providing plasticity and green strength. But modern high-end ceramics, in pursuit of high whiteness and high translucency, often:
- Reduce clay content
- Increase the proportion of lean materials such as quartz and feldspar
- Use refined clays that have been washed and de-ironed
3.5 Fast Drying Processes — Not Enough Time
Modern ceramic production pursues efficiency, with drying cycles getting shorter and shorter. But fast drying means:
- Rapid moisture evaporation and high shrinkage stress
- Not enough time for the body to release stress through creep
- Significantly increased cracking risk
The binder's core task is to build a temporary "skeleton" between particles.
Imagine: countless flexible threads stretched between loose sand grains, connecting a particle network barely held by water films into an integrated whole.
These hydrogen bonds act like countless tiny locks, firmly locking adjacent chains and particles together. Meanwhile, extended long chains entangle and pack together, forming a physical interlocking network. Hydrogen bond crosslinking and physical entanglement work together to greatly increase dry body strength.
When temperature reaches 400–600°C, the binder carbonizes and burns out, with no adverse effects on final product performance.
It only functions during the "fragile period" and leaves no trace after firing.
| Parameter | Without Binder | With Binder |
|---|---|---|
| Green Body Flexural Strength | Baseline | +20% to +200% |
| Demolding Damage Rate | High | Significantly reduced |
| Handling Corner Damage Rate | High | Greatly reduced |
| Drying Crack Rate | High | Noticeably improved |
| Drying Speed | Limited | Can increase by 30%+ |
| Production Yield | Relatively low | Significantly higher |
Because of thin walls, large format, complex shapes, high lean-material content, and fast drying — when a body possesses one or more of these features, its green strength is insufficient to safely carry it through all processes from forming to firing.
A binder is not "icing on the cake" — it's "help in time of need." It bridges and locks between particles, helping the body survive its most fragile stage, then quietly exits in the kiln.
Whether a body needs a binder depends on whether it can "hold up."
If it can hold up, no binder is needed; if it can't, a binder is essential.
And what determines whether it holds up is the combined effect of wall thickness, size, shape, formulation, and drying schedule.
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