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Ceramic Strength Enhancer Selection Guide: G301 vs G303 vs ZM01 for Tile & Sanitaryware


Time:

2026-05-11

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12-min read  |  Audience: Technical Directors, Ceramic Engineers, R&D Staff

Quick Answer:

To choose the right Goway ceramic body strength enhancer, match the chemical profile to your product type and process conditions:

  • FG-G301: Higher SiO₂ (65-70%) and Al₂O₃ (14-16%). Best for polished tiles and high-pressure porcelain pressing where higher green compaction and fired strength are needed. Typical dosage: 1.0-2.0%.
  • FG-G303: Balanced SiO₂ (60-65%) and Al₂O₃ (13-15%), LOI 6-7%. Suitable for glazed floor tiles, wall tiles and cost-sensitive formulations. Typical dosage: 0.8-1.8%.
  • FG-ZM01: Similar composition to FG-G303 (SiO₂ 60-65%, Al₂O₃ 13-15%, LOI 6-7%). Frequently used for sanitaryware and fast single-fire wall tiles. Typical dosage: 0.5-2.5%.

All three are compatible with STPP, SHMP and polycarboxylate deflocculants when addition sequence is correctly managed.

Selecting the right strength enhancer for ceramic tile and sanitaryware production involves balancing chemical composition, green strength targets, firing behavior and cost. This guide provides a practical comparison of three commonly used Goway enhancers — FG-G301, FG-G303 and FG-ZM01 — to help ceramic engineers and technical managers make informed decisions based on body formulation and production requirements.

The chemical composition of strength enhancers directly influences green body compaction, drying shrinkage, firing behavior and final product quality. Understanding the SiO₂/Al₂O₃ ratio, alkali metal content and loss on ignition (LOI) is essential for matching the right enhancer to specific ceramic bodies and production processes.

This guide covers chemical composition analysis, performance comparison methodology, application matching tables, dosage guidelines with strength improvement data, and compatibility with the deflocculant system (e.g., Sodium Tripolyphosphate (STPP) or Sodium Hexametaphosphate (SHMP)). It is intended for technical directors, ceramic engineers and R&D staff involved in body formulation and process optimization.

1. Chemical Composition Comparison: Understanding the Data

The following table presents the chemical composition of FG-G301, FG-G303 and FG-ZM01. These values represent typical ranges based on Goway product specifications and in-house testing (2025). Understanding these parameters is the first step in selecting the appropriate enhancer for your ceramic body.

Chemical Composition of FG-G301, FG-G303 and FG-ZM01 (Typical Values, wt%)
Parameter FG-G301 FG-G303 FG-ZM01 Analytical Method
SiO₂ 65-70% 60-65% 60-65% XRF / GB/T 21114
Al₂O₃ 14-16% 13-15% 13-15% XRF / GB/T 21114
Fe₂O₃ 1-2% 1-2% 1-2% XRF / GB/T 21114
Na₂O 1-2% 1-2% 1-2% XRF / GB/T 21114
CaO 1-2% 1-2% 1-2% XRF / GB/T 21114
MgO 2-3% 2-3% 2-3% XRF / GB/T 21114
K₂O 1-2% 1-2% 1-2% XRF / GB/T 21114
L.O.I (%) 5-6% 6-7% 6-7% GB/T 3299
Data source: Goway in-house testing (2025). Values are typical ranges — confirm with certificate of analysis for each batch. LOI = Loss on Ignition at 1000°C.
Chemical composition comparison bar chart: SiO2 and Al2O3 content in FG-G301, FG-G303 and FG-ZM01 ceramic strength enhancers

Fig. 1: SiO₂ and Al₂O₃ content comparison across FG-G301, FG-G303 and FG-G301 has the highest SiO₂ (65-70%) and Al₂O₃ (14-16%), which contributes to its suitability for polished tile and high-pressure porcelain pressing applications. (Goway in-house testing, 2025.)

Insight SiO₂/Al₂O₃ Ratio Matters: FG-G301 carries a higher absolute Al₂O₃ (14-16%) compared to FG-G303 and FG-ZM01 (13-15%). The higher Al₂O₃ in FG-G301 may contribute to improved refractoriness and green compaction in certain body formulations. However, the practical difference depends on the overall body matrix and firing profile.

1.1 How Does Chemical Composition Affect Ceramic Green Strength?

SiO₂ (Silicon Dioxide): The primary network former in ceramic bodies. Higher SiO₂ content (as in FG-G301, 65-70%) may improve green body compaction and reduce drying shrinkage. In the fired body, SiO₂ contributes to the silicate network and influences thermal expansion behavior.

Al₂O₃ (Aluminum Oxide): Increases refractoriness and mechanical strength after firing. FG-G301 has slightly higher Al₂O₃ (14-16%) compared to FG-G303 and FG-ZM01 (13-15%). This may make FG-G301 more suitable for bodies requiring higher fired strength or where higher firing temperatures are used.

Fe₂O₃ (Iron Oxide): All three products maintain Fe₂O₃ at 1-2%. While iron is a common flux, levels below 2% typically do not cause significant body darkening in oxidized firing. For products requiring high whiteness (e.g., premium polished tiles), consider additional body composition adjustments and firing atmosphere control.

Alkali Metals (Na₂O, K₂O, CaO, MgO): These act as fluxes during firing, promoting densification at lower temperatures. The total alkali content (Na₂O + K₂O + CaO + MgO) is similar across all three products (approximately 5-9%). FG-G303 and FG-ZM01 have slightly higher LOI (6-7% vs. 5-6%), which may indicate different organic additive contents that affect green strength development mechanisms.

Caution Alkali Content and Firing Temperature: Higher alkali metal content promotes fluxing and may reduce the required firing temperature. However, excessive alkali can increase the risk of over-firing or glaze-body compatibility issues. Always verify firing behavior with small-scale trials before adjusting enhancer selection or dosage.

2. Application Matching: Which Enhancer for Which Product?

The selection of strength enhancer should be based on the specific ceramic product type, body formulation characteristics, and production process parameters. The following table provides a practical matching guide for common ceramic products.

Application Matching Table — FG-G301, FG-G303 and FG-ZM01 for Common Ceramic Products
Product Type Recommended Enhancer Why This Choice Typical Dosage
Polished Tiles FG-G301 Higher SiO₂ and Al₂O₃ may improve green compaction and reduce drying shrinkage, which is important for polished tile quality 1.0-2.0%
Glazed Floor Tiles FG-G303 or FG-ZM01 Balanced composition provides adequate green strength with cost efficiency 0.8-1.8%
Wall Tiles (Fast Single-fire) FG-G303 or FG-ZM01 Moderate Al₂O₃ and appropriate alkali content suit faster firing cycles 0.5-1.5%
Sanitaryware (Slip Casting) FG-G303 or FG-ZM01 Compatible with slip casting processes; helps improve green strength before firing 1.0-2.5%
Porcelain Tiles (High-pressure pressing) FG-G301 Higher Al₂O₃ may support higher fired strength requirements of porcelain 1.2-2.2%
Cost-sensitive Formulations FG-G303 or FG-ZM01 Lower cost per unit while still providing measurable green strength improvement 0.5-1.5%
Selection notes: These are starting-point recommendations. Actual selection should consider existing body formulation, press capability, drying system design and quality targets. FG-G303 and FG-ZM01 have similar chemical compositions; the choice between them may depend on particle size distribution, organic additive types, or specific process requirements. Consult Goway technical support for tailored recommendations.
Insight Polished Tiles vs. Glazed Tiles: Polished tiles typically require higher green strength to withstand the polishing process without surface defects. FG-G301's higher SiO₂ content (65-70%) may contribute to a more compact green body structure. Glazed tiles, especially wall tiles, can often achieve adequate performance with FG-G303 or FG-ZM01, which may offer better cost efficiency.

2.1 Body Formulation Considerations

When selecting an enhancer, consider the existing body formulation's SiO₂/Al₂O₃ ratio. If the base body already has high Al₂O₃ from ball clay or kaolin, adding FG-G301 may push the ratio too high, potentially requiring higher firing temperatures. In such cases, FG-G303 or FG-ZM01 with slightly lower Al₂O₃ may be preferable.

Conversely, if the body is SiO₂-rich (e.g., high quartz content), FG-G301 can help balance the composition and improve fired strength. The alkali metals in all three enhancers act as supplemental fluxes, which may allow slight reductions in feldspar content while maintaining adequate firing behavior.

3. Dosage Guidelines: Expected Strength Improvement at Different Addition Rates

The relationship between enhancer dosage and green strength improvement is not always linear. Low additions may provide significant relative improvement, while higher additions may show diminishing returns. The following table presents typical strength improvement data based on laboratory press trials and published ceramic engineering literature.

Typical Green Strength Improvement vs. Enhancer Dosage (Laboratory Press Trials, 30 MPa Pressing Pressure)
Dosage (% by weight) Expected Green Strength Increase (%) Drying Shrinkage Change (%) Notes
0.5% 15-25% -0.2 to 0.0% Good starting point for cost-sensitive formulations
1.0% 25-35% -0.3 to -0.1% Common choice for glazed floor tiles
1.5% 30-45% -0.5 to -0.2% Good balance of strength and cost for polished tiles
2.0% 35-50% -0.6 to -0.3% Suitable for sanitaryware and high-pressure pressing
2.5% 40-55% -0.8 to -0.4% May show diminishing returns beyond this level
3.0% 40-60% -1.0 to -0.5% Highest practical dosage; verify cost-benefit ratio
Source: Laboratory press trials based on typical tile body formulations (SiO₂ 68%, Al₂O₃ 18%, other 14%), 30 MPa pressing pressure, 110°C drying. Green strength measured by three-point bending test (GB/T 3810.4). Drying shrinkage change is relative to control sample without enhancer. Values are typical ranges — actual results depend on body composition, press pressure, drying conditions and enhancer type.

Green strength improvement (%) versus dosage (%) curve for FG-G301 ceramic strength enhancer in polished tile body at 30 MPa pressing pressure

Fig. 2: Typical green strength improvement curve for FG-G301 at 30 MPa pressing pressure in a standard polished tile body. Diminishing returns are observed beyond 2.5% addition. (Based on laboratory press trials; values are indicative, not absolute specifications.)

FG-G301 Typical Performance Parameters (In-house Testing, 2025)

Recommended dosage range
1.0-2.0% (by weight of dry body mix)
Green strength increase (typical)
30-45% at 1.5% addition (laboratory conditions)
Drying shrinkage change
-0.5 to -0.2% relative to control
Particle size (D50)
Approximately 5-15 μm (product-specific)
Moisture tolerance
Stable in spray-dried granules at 5-7% moisture

FG-G303 / FG-ZM01 Typical Performance Parameters (In-house Testing, 2025)

Recommended dosage range
0.8-2.5% (by weight of dry body mix)
Green strength increase (typical)
25-50% at 1.5-2.0% addition (laboratory conditions)
Drying shrinkage change
-0.3 to -0.6% relative to control
Particle size (D50)
Approximately 5-15 μm (product-specific)
Organic additive type
May differ between FG-G303 and FG-ZM01; confirm with Goway technical data sheet
Caution Diminishing Returns at High Dosage: Adding more than 2.5-3.0% enhancer may show diminishing returns in strength improvement while increasing raw material cost. In some cases, excessive enhancer may slightly increase drying shrinkage or affect glaze adhesion. Always determine the optimal dosage through laboratory trials before production-scale adoption.

4. Deflocculant Compatibility: Using Enhancers with STPP, SHMP and Polycarboxylates

Strength enhancers and deflocculants are often used together in ceramic body formulations. However, their interaction can affect slurry viscosity, granule properties and final product quality. Understanding compatibility and proper addition sequence is essential.

4.1 Are Ceramic Strength Enhancers Compatible with STPP and Polycarboxylate Deflocculants?

FG-G301, FG-G303 and FG-ZM01 are compatible with commonly used ceramic deflocculants, including:

  • Sodium Tripolyphosphate (STPP): Commonly used for ceramic slip deflocculation. Compatible with all three enhancers when added in proper sequence.
  • Sodium Hexametaphosphate (SHMP): Provides strong deflocculation effect, particularly in hard-water ceramic slurry conditions. Compatible, but monitor slurry viscosity changes after enhancer addition.
  • Polycarboxylate dispersants: Synthetic polymers with high deflocculation efficiency. Generally compatible, but avoid simultaneous high-concentration addition with enhancers.
  • Silicate-based deflocculants: Used in some sanitaryware formulations. Compatible with FG-G303 and FG-ZM01.

4.2 Recommended Addition Sequence

The addition sequence affects how deflocculants and strength enhancers interact in the slurry. The following sequence is recommended based on ceramic engineering practice:

Recommended Addition Sequence for Deflocculant + Strength Enhancer Systems
Step Additive Timing Purpose
1 Deflocculant (STPP / SHMP / Polycarboxylate) During ball milling Establish slurry fluidity, disperse particles
2 Strength Enhancer (FG-G301 / G303 / ZM01) After milling, before spray drying Avoid competitive adsorption during milling; allow deflocculant to work first
3 Additional deflocculant (if needed) Before spray drying Fine-tune slurry viscosity if enhancer addition increased viscosity
Note: This sequence is a general recommendation. Specific formulations may require adjustment. Avoid premixing deflocculant and enhancer in high-concentration stock solutions. (Based on ceramic processing literature and field practice, 2018-2024.)
Insight Why Add Deflocculant First? Deflocculants work by adsorbing onto particle surfaces and creating electrostatic repulsion. Strength enhancers, especially those containing organic polymers, may also adsorb onto particles and affect zeta potential. Adding deflocculant first allows it to establish dispersion, after which the enhancer can be added without interfering with the deflocculation mechanism. Some enhancers may slightly increase slurry viscosity; this can be managed by adding a small additional amount of ceramic-grade STPP dispersant before spray drying.

4.3 Troubleshooting: Why Does Slurry Viscosity Increase After Adding Strength Enhancers?

Troubleshooting: Slurry Viscosity Changes After Enhancer Addition
Symptom Possible Cause First Check Corrective Direction
Slurry viscosity increases after enhancer addition Enhancer adsorbing onto particles and reducing deflocculant effectiveness Measure slurry viscosity before and after enhancer addition Add 0.05-0.10% additional deflocculant; ensure enhancer is added after deflocculant
Spray-dried granules too wet or uneven Enhancer affecting granule formation or moisture distribution Check granule particle size distribution and moisture content Adjust spray drying parameters (inlet temperature, atomizer speed); consider reducing enhancer dosage by 0.2-0.3%
Green body lamination or delamination Excessive enhancer dosage or poor granule compaction Check pressing pressure, die filling uniformity, and granule moisture Reduce enhancer dosage; increase pressing pressure; verify granule moisture is uniform
Corrective directions are starting points. Validate with laboratory or pilot trials before production-scale changes. (Based on published ceramic processing literature and field practice.)

5. How to Select and Test Ceramic Strength Enhancers: Step-by-Step Protocol

Laboratory testing before production adoption is strongly recommended. The following step-by-step protocol provides a structured approach to evaluating FG-G301, FG-G303 and FG-ZM01 for your specific ceramic body.

  1. Step 1: Define body type and performance targets Identify the ceramic body type (polished tile, glazed tile, sanitaryware), target green strength increase (%), and any firing temperature constraints. Review current body formulation to understand existing Al₂O₃/SiO₂ ratios and alkali content. Document current green strength, drying shrinkage and firing behavior as baseline (control) values.
  2. Step 2: Select candidate enhancer based on application table Use the Application Matching Table in Section 2 to shortlist 1-2 candidate products. For polished tiles, consider FG-G301. For glazed tiles or cost-sensitive formulations, FG-G303 or FG-ZM01 may be options. For sanitaryware, FG-G303 or FG-ZM01 are frequently used. Prepare at least 5 kg body mix per trial condition.
  3. Step 3: Run laboratory press trials with 3 dosage levels Prepare laboratory pressed samples at 0.5%, 1.5% and 2.5% addition rates (by weight of dry body mix). Add STPP deflocculant first during ball milling, then add enhancer after milling. Measure green strength (MPa, three-point bending per GB/T 3810.4), drying shrinkage (%), water absorption after firing (%), and visual defects. Compare against control samples. Prepare at least 10 test pieces per condition for statistical reliability.
  4. Step 4: Check deflocculant compatibility If using STPP, SHMP or polycarboxylate deflocculants, verify that enhancer addition does not negatively affect slurry fluidity. Measure slurry viscosity (Brookfield or Ford Cup) before and after enhancer addition. If viscosity increases by more than 20%, consider adding 0.05-0.10% additional deflocculant.
  5. Step 5: Validate at pilot scale and optimize dosage After laboratory confirmation, run pilot spray drying and pressing trials. Monitor granule properties (particle size distribution, moisture uniformity), press performance (filling behavior, ejection quality), and green body quality. Adjust dosage in 0.3% increments to find the optimal addition rate. Document all parameters and results for future reference.

6. Industry Reference Data: Typical Operating Parameters for Ceramic Strength Enhancers

The following table provides reference parameter ranges based on published ceramic processing literature, equipment manufacturer recommendations, and typical industry practice (2015-2024). These values are for benchmarking and should not be used as absolute specifications without verification in your specific process conditions.

Reference Parameter Ranges for Ceramic Strength Enhancer Application
Parameter Typical Range Notes
Enhancer dosage (by weight of dry body) 0.5-3.0% Most common: 1.0-2.0%. Higher dosage may show diminishing returns.
Green strength increase (typical) 15-60% Depends on body formulation, press pressure, enhancer type and dosage.
Drying shrinkage change -1.0 to 0.0% Negative value = shrinkage reduction. Beneficial for size consistency.
Pressing pressure (typical for tile) 25-40 MPa Higher pressure may improve green strength further when using enhancers.
Drying temperature 100-150°C Ensure uniform drying to avoid cracking, especially with higher enhancer dosage.
Firing temperature (fast single-fire) 1050-1150°C Enhancer alkali content may allow slight reduction in firing temperature.
Slurry viscosity (after deflocculant + enhancer) 200-600 mPa·s Measure with Brookfield viscometer. Adjust deflocculant if too high.
Source: Published ceramic processing literature, equipment manufacturer recommendations, and typical industry practice, 2015-2024. Values are reference ranges — not absolute specifications. Always validate with your specific body formulation and production conditions.

7. Frequently Asked Questions

Q1: What is the typical dosage range for ceramic strength enhancers, and how much green strength improvement can I expect?
Typical dosage ranges from 0.5% to 3.0% by weight of dry body mix. Lower additions (0.5-1.0%) may increase green strength by 15-25%. Medium additions (1.0-2.0%) may provide 25-40% improvement. Higher additions (2.0-3.0%) may achieve 40-60% strength gain. Actual results depend on body composition, press pressure, and drying conditions. Always verify with laboratory press trials before production adoption. For more on deflocculant selection, see our spray drying dispersant selection guide.
Q2: Can FG-G301, FG-G303 and FG-ZM01 be used with STPP or polycarboxylate deflocculants?
Yes. All three enhancers are compatible with common deflocculants including Sodium Tripolyphosphate (STPP), SHMP and polycarboxylates. The recommended addition sequence is: add deflocculant first during ball milling, then add the strength enhancer after milling or before spray drying. Avoid premixing both additives in high-concentration stock solutions, which may cause localized competitive adsorption. If slurry viscosity increases after enhancer addition, add 0.05-0.10% additional deflocculant and re-measure.
Q3: Which enhancer is best for polished tiles requiring high green strength?
FG-G301 may be more suitable for polished tiles. Its higher SiO₂ content (65-70%) and Al₂O₃ (14-16%) contribute to improved green compaction and reduced drying shrinkage, which are important for polished tile quality. In plant trials, 1.5-2.0% FG-G301 addition has been associated with 30-45% green strength improvement in polished tile bodies. Laboratory validation is recommended before switching enhancers.
Q4: How does Al₂O₃ content affect firing temperature and body whiteness?
Higher Al₂O₃ generally increases refractoriness, potentially requiring higher firing temperatures for full densification. FG-G301, FG-G303 and FG-ZM01 all maintain Fe₂O₃ at 1-2%, which helps limit body darkening. For bodies requiring higher whiteness, consider matching enhancer selection with lower-iron kaolin clay and controlled firing atmosphere. The alkali metals in these enhancers act as fluxes and may allow slight reductions in firing temperature (10-20°C), but this depends on overall body composition.
Q5: What is the difference between FG-G303 and FG-ZM01 in chemical composition?
According to available product data, FG-G303 and FG-ZM01 have similar chemical compositions: SiO₂ 60-65%, Al₂O₃ 13-15%, Fe₂O₃ 1-2%, Na₂O 1-2%, CaO 1-2%, MgO 2-3%, K₂O 1-2%, LOI 6-7%. The key differences may relate to particle size distribution, organic additive types, or process-specific formulation designs. Confirm specific performance differences with Goway technical support before large-scale adoption. Requesting samples of both products for side-by-side comparison is recommended.

Need Help Selecting the Right Strength Enhancer?

Goway's technical team can provide tailored recommendations based on your body formulation, production process and quality targets. Request a technical consultation or product samples for laboratory evaluation.

Request Technical Consultation Request Sample + TDS
About this article: Prepared by the Goway Chemical Technical Team based on published ceramic processing literature, industry practice, and process engineering experience spanning 15+ years of ceramic additive applications. Goway Chemical is a Foshan-based manufacturer of ceramic additives and phosphate chemicals (ISO 9001 certified; REACH compliant), with annual production capacity of 30,000 tonnes for ceramic additives. For product enquiries: [email protected].

Technical data and parameter ranges cited in this article are drawn from publicly available literature and represent typical industry reference values. They should not be used as specifications without verification in your specific process conditions.

Reviewed by: Goway Ceramic Additives Technical Application Team
Technical scope: ceramic body formulation, strength enhancers, deflocculant compatibility, press trial methodology
Reference basis: This article synthesizes information from ceramic engineering textbooks (e.g., Ricceri, 2014; Ryan, 2005), peer-reviewed journals (Ceramics International, Journal of the European Ceramic Society), and Goway in-house testing (2025). Typical parameter ranges are compiled from equipment manufacturer guidelines and industry practice surveys (2015-2024).

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